DIRECTOR DE PROIECT:
Dr. Tiseanu Carmen
PROJECT MANAGER:
Dr. Tiseanu Carmen
Email:
carmen.tiseanu@inflpr.ro
DURATA PROIECTULUI:
2006 - 2008
PROJECT
DURATION :
2006 - 2008
CONDUCATOR PROIECT:
INSTITUTUL NATIONAL DE CERCETARE-DEZVOLTARE
PENTRU FIZICA LASERILOR, PLASMEI SI RADIATIEI INFLPR DIN BUCURESTI
PARTENERI:
1. UNIVERSITATEA
DIN BUCURESTI (Prof.
V.I. Parvulescu)
2. UNIVERSITATEA
BABES-BOLYAI DIN CLUJ-NAPOCA ( Prof. S.
Simon)
3. INSTITUTUL
NATIONAL DE CERCETARE-DEZVOLTARE PENTRU FIZICA MATERIALELOR INCDFM DIN
BUCURESTI
( Dr. A. Manea )
MAIN
OBJECTIVES
• Nanocomposites
(or hybrid organic-inorganic materials) with lanthanides (Ln3+)
represent a hot topics research worldwide as they offer the possibility
of fine tuning the optical response by controlling Ln3+-
host interactions at a nanometric scale. While the coordination
chemistry of lanthanide’s ions is well- known and several synthesis
methods of Ln-nanocomposites are currently developed, many of the
problems remained unsolved are related to the basic mechanisms of
luminescence. The broad objective of the project is to
investigate structure- photophysical properties in Ln3+-nanocomposites. A great
variety of structural investigation methods are considered: (FT-IR,
XRD, NMR, ESR, XPS, luminescence spectroscopy).
• The study
of the optical properties is based on a comprehensive spectroscopic
instrumentation and methods such as optical absorption, excitation
spectroscopy, steady-state and time-resolved laser induced luminescence
spectroscopy with temporal resolution from ps to ns. The expected
results concern (1) synthesis of novel nanocomposites with Ln3+
with emission spanning a broad spectral domain, from UV/VIS to NIR and
lifetimes varying form several µs to ms and and (2) in-depth
investigation and modeling of the excited state dynamics of Ln3+
in nanocomposites as well as the confinement effects
induced by the nanocomposites structure on the luminescence
properties. Applications to photonics, but also to sensing
and environment are addressed.
RESULTS
Publications
6.
C. Tiseanu, V. Lorenz-
Fonfria, A. Gessner, M.
Kumke, V.I.
Parvulescu, "Photoluminescence
study of terbium-exchanged USY
zeolites: Number of species, luminescence decays and decay-associated
spectra,”
J.
Appl. Phys. 104(1-9),
033530 (2008).
5.
C.
Tiseanu, V.I.
Parvulescu, A. Geßner, M. Kumke, J. Martens, “Europium (III)
- an efficient luminescence probe for the Si to Al ratio
and silylation effects in microporous-mesoporous Zeogrid materials,”
J. Phys. Chem B. 112(34),
10552-10562 (2008).
4.
C. Tiseanu, A. Geßner, M.U.
Kumke, "Dehydration and
rehydration effects on the photoluminescence properties of
terbium-exchanged
MFI type materials,” J. Non-Cryst. Solids 354
(18), 1969-1975 (2008).
3.
C. Tiseanu, V. Lorenz-
Fonfria, A. Gessner, M.
Kumke, “Comparative study of
terbium-exchanged
zeolites functionalized with alkoxysilanes,” J.
Mater. Sci.
Electron. Vol 20,
Supplement 1, 312-316 (2009).
2. C. Tiseanu, A. Gessner, M. Kumke, B. Gagea, V.
Parvulescu, J. Martens, “Luminescence spectra and
dynamics of lanthanides doped microporous- mesoporous materials,” J.
Lumin. 128
(5-6), 751-753 (2008).
1.
C.
Tiseanu, B. Gagea, V.I. Parvulescu, V. Lorenz-Fonfria, A. Geßner,
M.U. Kumke, "Investigation
of the hydrophobization efficiency of terbium-exchanged BEA zeolites by
means
of FT-IR, TGA, physical adsorption and time-resolved photoluminescence,"
Langmuir 23 (12), 6781-6787 (2007).
Conferences
8. C. Tiseanu, V.I. Parvulescu, A. Gessner, M.U. Kumke, “Siliceous
grafted Eu3+-
and Tb3+ complexes: structural characterization
and luminescence properties,”
15th International Conference on
Luminescence and Optical Spectroscopy of Condensed Matter (ICL’08),
Lyon,
France, 7-11 July, 2008.
7. C. Tiseanu, A. Gessner, M. U. Kumke, “Time-resolved
photoluminescence
proprties of terbium- exchanged microporous-mesoporous materials,” 15th
International Conference on Luminescence and Optical Spectroscopy of
Condensed
Matter (ICL’08), Lyon, France, 7-11 July, 2008.
6. C. Tiseanu, V.A. Lorenz-Fonfria, E. Cotoi, “Species-related
luminescence-structure
relationships in Eu3+-exchanged
microporous-mesoporous materials,“ 2nd
International Conference on Advanced Nano Materials (ANM 2008), Aveiro,
Portugal, June 22-25, 2008.
5. C. Tiseanu, V.I.
Parvulescu, C. Paun, S. Dobre, A.
Gessner, M.U. Kumke, E. Cotoi, “Luminescence properties of Eu3+,
Tb3+
and Nd3+ doped ionic liquids immobilized on
mesoporous silica
supports,” 2nd International Conference on Advanced Nano
Materials (ANM
2008), Aveiro, Portugal, June 22-25, 2008.
4. C.
Tiseanu, A. Gessner, M.U.
Kumke, B. Gagea, V.I. Parvulescu, J. Martens, "Luminescence spectra and
dynamics of lanthanides doped microporous-
mesoporous materials," 16th
International Conference on Dynamical Processes in Excited States
of Solids, Segovia, Spain, June, 17-22, 2007.
3. C. Tiseanu, V.A. Lorenz-Fonfria, A. Gessner, M.U. Kumke, “Comparative
study of terbium-exchanged zeolites
functionalized with alkoxysilanes,” the International Conference on
Optical,
Optoelectronic and Photonic Materials and Applications, London,
England, 30
July - 03 August 2007.
2. A. Gessner, M.U. Kumke and C. Tiseanu, "Luminescence properties of
lanthanide’s doped MFI-type materials,” the Bunsen Conference, Graz,
Austria,
17-19 May, 2007.
1.
A. Gessner, M.U. Kumke and
C. Tiseanu, “Luminescence properties of lanthanide’s doped MFI-type
materials,”
ICP2007 - XXIII International Conference on Photochemistry, Cologne,
Germany,
29 July - 3 August 2007.